Projectile shapes of the superdetonative ram accelerator have great effects on shock structures, detonation wave formation, and ram acceleration characteristics. In this study, cone-cylinder-cone, a baseline projectile configuration of the superdetonative combustion mode, double-cone configurations and power-law shape, have been numerically investigated to analyze the effect of the front/rear configuration changes, on the flow field around the projectile, detonation wave formation process, and projectile acceleration characteristics. Hence, a ram projectile configuration with conspicuously improved acceleration characteristics has been proposed by adjusting the double cone angle and height. The results provide useful information for the ram accelerator design optimization study.