This paper introduces the monitoring scheme of laser welding quality using neural network. The developed monitoring scheme detects light signal emitting from plasma formed above the weld pool with optic sensor and DSP-based signal processor, and analyzes to give a guidance about the weld quality. It can automatically detect defects of laser weld and further give an information about what kind of defects it is, specially partial penetration and porosity among the interior defects. Those could be detected only by naked eyes or X-ray after welding, which needs more processes and costs in mass production. The monitoring scheme extracts four feature vectors from signal processing results of optical measuring data. In order to classify pattern for extracted feature vectors and to decide defects, it uses single-layer neural network with perceptron learning. The monitoring result using only the first feature vector shows confidence rate in recognition of 90%($pm$5) and decides whether normal status or defects status in real time.