- 방전처리에 의한 Polypropylene섬유의 표면개질
- ㆍ 저자명
- 허만우,이창재,강인규,한명호,김삼수,임학상
- ㆍ 간행물명
- 韓國染色加工學會誌
- ㆍ 권/호정보
- 1999년|11권 2호|pp.27-37 (11 pages)
- ㆍ 발행정보
- 한국염색가공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Polypropylene(PP) films were treated with plasma glow discharge to produce peroxy radicals on the surfaces. The peroxy radicals formed on the PP film surfaces were subsequently used for the graft polymerization of acrylic acid and acrylamide in an aqueous solution by heating, respectively. Introduction of acrylic acid and acrylamide on the PP film could be confirmed by the observation of carbonyl and primary amine absorptions based on carboxylic acid and amide, respectively. And introduction of functional group could be confirmed by weight analysis and ESCA. The water contact angle(90$^{circ}$) of PP film was constant, irrespective of elapsed time, while plasma-treated and functional monomer-grafted PP films were slowly increased with elapsed time, showing the rearrangement of surface polar groups in air condition. The water contact angle$(90^circ)$ of PP film was decreased by the plasma treatment$(56^circ)$ and further decreased by the grafting of acrylic acid$(34^circ)$ and acrylamide$(37^circ)$, indicating increased hydrophilicity of the modified surfaces. The water contact angle of plasma-treated PP film increased a little as time elapsing. The half-life periods of surface voltage on acrylic acid-(31sec) and acrylamide-grafted PP(42sec) were significantly decreased when compared to those on PP(950sec) and plasma-treated PP film(241sec). In the experiments using acid, basic and disperse dyes, absorbance and $Delta{E}$ values of functional monomer-grafted PP films were significantly increased than that of oxygen plasma-treated one.