The change of the coefficients of thermal expansion(CTE) of Carbon/Epoxy was investigated for the temperature variation and a prediction model for the change of CTE was proposed. Elastic properties and CTEs in the principal material directions were measured in the range of room temperature to cure temperature and characterized as functions of temperature. By applying the characterized properties to the classical lamination theory, a computational method to predict the change of CTEs of a general laminate for temperature variation was proposed. the coefficients of thermal expansion of laminates with various stacking sequences were measured and compared with those predicted. Good agreements between the predicted results and the experimental data show that the c hanges of CTEs of a general laminate for temperature variation can be predicted well by using the proposed method.