Robot calibration is very important to improve the accuracy of robot manipulators. However, the calibration procedure is very time consuming and laborious work for users. In this paper, we propose a method of relative error compensation to make the calibration procedure easier. The method is completed by a Pi-Sigma network architecture which has sufficient capability to approximate the relative relationship between the accuracy compensations and robot configurations while maintaining an efficient network learning ability. By experiment of 4-DOF SCARA robot, KIRO-3, it is shown that both the error of joint angles and the positioning error of end effector are drop to 15$\%$. These results are similar to those of other calibration methods, but the number of measurement is remarkably decreased by the suggested compensation method.