Proximate composition, sterol and $alpha$-tocopherol ($alpha$-Toc) contents of 35 species of marine invertebrates (13 species of Bivalvia, 10 species of Gastropoda, 4 species of Cephalopoda, 4 species of Crustacea, 2 species of Ascidacea and 2 species of Holothuroidea), which caught off the coast of Tongyeong of the Southern sea (Nam-Hae), Korea, were determined. Protein content showed relatively high level in herbivorous (seaweed feeder) and carnivorous species such as Gastropoda ($17.2pm4.30\%$), Crustacea ($16.8pm4.06\%$) and Cephalopoda ($15.3pm3.24\%$), but showed low in plankton feeder and mud swallow such as Bivalvia ($11.8pm2.49\%$), Ascidacea ($8.20pm1.00\%$) and Holothuroidea ($3.94pm1.13\%$). Total lipid (TL) content was low in most marine invertebrates, ranged from $0.24\%$ (blue colored sea cucumbers) to $1.96\%$ (sea squirts). Ascidacea contained the largest amount of TL in all samples, while Holothuroidea contained the smallest amount of TL, and other classes contained about $1\%$ of TL. Carbohydrates was rich in plankton feeder and Herbivorous species (seaweed feeder) such as Ascidacea ($6.60pm4.53\%$), Bivalvia ($3.15pm1.82\%$) and Gastropoda ($3.02pm1.61\%$), while poor in carnivorous species such as Crustacea ($0.52pm0.57\%$) and Cephalopoda ($1.00pm0.63\%$). Moisture content was highest in Holothuroidea ($92.0pm1.94\%$) and the lowest in Gastropoda ($77.0pm1.95\%$): There were negative correlations between moisture and protein content, or TL, between protein and TL content; y= -0.8716x+184.452 (r=-0.87, p<0.001), $y=128.52e^{-0.0601x}$ (r=-0.55, P<0.001), $y=6.3047e^{-0.0904x}$(r=-0.42, P<0.02), respectively. Sterol content was ranged from 56 mg/100 g edible portion of red colored sea cucumbers to 216 mg/100 g edible portion of cockle and was high in the following order; Cephalopoda (148 $pm$30.0mg)>Bivalvia (121$pm$35.0mg)>Gastropoda (118$pm$20.0mg)>Crustacea (116$pm$31.0mg)>Ascidacea (78.0$pm$2.00 mg)>Holothuroidea(62.0$pm$8.00 mg). Crustacea contained 1$~$2 mg $alpha$-Toc/100 g edible portion whereas other classes contained trace or less than 1 mg/100 g of edible portion.