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Ni계 합금으로 브레이징된 Fe-Cr-Al 합금 접합부의 주기산화거동
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  • Ni계 합금으로 브레이징된 Fe-Cr-Al 합금 접합부의 주기산화거동
저자명
문병기,최철진,박원욱,Mun. Byeong-Gi,Choe. Cheol-Jin,Park. Won-Uk
간행물명
硏究論文集 : 한국기계연구원
권/호정보
1999년|29권 2호|pp.141-149 (9 pages)
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한국기계연구원
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Brazing of Fe-Cr-Al alloy was carried out at $1200^{circ}C$ in vacuum furnace using nickel-based filler metals : BNi-5 powder(Ni-Cr-Si-Fe base alloy} and MBF-50 foil (Ni-Cr-Si-B). The effect of boron content on the stability of oxide scale on the brazed joint was investigated by means of cyclic oxidation test performed at $1050^{circ}C$ and $1200^{circ}C$. Apparently, the joints brazed with MBF-50 containing boron showed relatively stable oxidation rates compared to boron-free BNi-5 at both temperatures. However, it was considered that the slower weight loss of MBF-50 brazed specimen wasn’t resulted from the low oxidation rate but from the spallation of oxide layer. The oxide layer consisted of thick spinel oxide on the surface and $Al_2 O_3$ internal oxide layer along the interface between mother alloy and braze, the mother alloy was also eroded seriously by the formation of spinel oxides such as $FeCr_2 O_4$ and $NiCr_2 O_4$ on the surface, likely to be induced by the change of oxide forming mechanism due to diffusion of boron from the braze. On the contrary, the joint brazed with BNi-5 showed the good oxidation resistance during the cyclic oxidation test. It seems that the oxidation can be retarded by the formation of stable $Al_2 O_3$ layer at the surface.