We have developed a new relief valve which is a safety device for the domestic gas-fired hot water boilers. The relief valve has been designed to expand the inner diameter of the inlet, the outlet and the seat of the valve considering the relief capacity, and also to separate the spring from the room heating water. Therefore, we could minimize the adhesion and/or obstruction of the inlet and the corrosion phenomena of the spring which used to be the problem of the conventional relief valves. Test results of the developed relief valve showed that the performance of the opening pressure, reseating pressure, tightness, endurance were excellent, and the operating boiler with developed relief valve was evaluated as very good. The standardization and application of the relief valve can provide the advantage of component exchange and easy maintenance and repair.