In this experimental study we proposed the double dielectric barrier discharge (DDBD) reactor to produce as high an electric field as possible. The experiment are conducted for applied voltage from 15 to 20[kV], $1~4[ell/min]$ of gas flow rate and 120[Hz] and 240[Hz] of pulse rate. Superposition discharge(SPD) generated in DDBD which combined the surface discharge with the silence discharge was the most effective to reduce the $NO_x$. In the decomposition efficiency per watt, the low pulse rate gave better efficiency than the high pulse rate. However in DeNOx rate, the high pulse rate gave better performance than the low pulse rate. $NO_x$ removal rate and efficiency increased with increasing the applied voltage in all reactors.