A new photo-polymer material of the copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy)chalcone-cholesteryl methacrylate) for homeotropic alignment was synthesized and the electro-optical (EO) performance for the photo-aligned vertical-aligned (VA)-LC display (LCD) was studied. Good thermal stabilities of synthesized copolymer were obtained by TGA(Thermogravimetric Analysis) measurement. Good voltage-transmittance (V-T) and response time characteristics for the photo-aligned VA-LCD with polarized UV exposure in oblique direction($ heta$$_{i}$=30$^{circ}$) on a copolymer-1 (2%) surfaces for 1 min were observed. but, light leakage in the off-state was observed. Therefore, we achieved excellent V-T and response time characteristics for the photo-aligned VA-LCD with UV exposure on a copolymer-3 (30%) surfaces for 3 min.n.