This paper proposes a new algorithm classifing same hues in order toe estimate the spectral reflectance of object from 3 band color image information. To estimate the spectral reflectance of object, the conventional estimation methods are required of 5 or 9 band digital color values. The 5 or 9 band image acquisition systems are required of 5 or 3 times same work for color image acquisition process. To solve the above problems, we propose a new method that can be estimated spectra reflectance estimation of object. The proposed method is to classify same hues corresponding a color stimulus, by using hue angle and chroma vector of a color stimulus. The classified same hues are used as the population corresponding a color stimulus. The range of same hue is estimated by the cumulative proportional ration according to the number of basis function.