Heat transfer characteristics of a heat exchanger for low temperature waste heat recovery using oscillating capillary tube heat pipe were evaluated against the charge ratio variation of working fluid and various working fluids. R-l42b, R-22 and R-290 were used as working fluids. The heat exchanger was composed of heat pipe with capillary tube bundles, having a 2.6mm in outer diameter, 1.4mm in inner diameter with 101m long, and 40 turns. Charge ratio of working fluid was 40% and 50%. Water was used as secondary fluid. Inlet temperature and mass velocity for each secondary fluid were 297 K, 280 K and9~27 kg /$m^2s$,, respectively. From experimental results, it was found that heat transfer performance of R-22 was higher than those of R-l42b and R-290 and it was proportional to Figure of merit for thermosyphons. As a result, it was thought that R-22 was the most suitable working fluid of waste heat recovery for low temperature waste heat recovery.