In order to investigate the effectiveness of methanol, which has high latent heat of evaporation and oxygen contents, for DI diesel engine performance and exhaust emission, the methanol was injected at the suction port of DI diesel engine. The injector used for test was conventional gasoline engine injector and controlled the quantity of methanol per cycle by the power supply controller which designed specially for injector. The results shown that the maximum pressure point was delayed, the value of maximum pressure was decreased, and the concentrations of both NOx and Soot were decreased, as the methanol injection quantity increased, and also the thermal efficiency of engine injected methanol under the high load condition was similar to no methanol injection but under the medium load condition was decreased within the experimental conditions.