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Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts
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  • Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts
  • Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts
저자명
Park. Yong-Joon,Pyo. Hyung-Ryul,Kim. Do-Yang,Jee. Kwang-Yong,Kim. Won-Ho
간행물명
Journal of the Korean Nuclear Society
권/호정보
2000년|32권 5호|pp.514-520 (7 pages)
발행정보
한국원자력학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The mechanism of corrosion behavior has to be understood clearly to select an optimum material for handling molten salts to be used in the oxide reduction process of PWR spent fuel. In this study, the oxidation states of corrosion products on the surface of Inconel 600 and 800H as well as their chemical compositions and structural informations were determined by using XPS, ICP-AES, AAS, EPMA and XRD after the corrosion experiment with lithium molten salts at 75$0^{circ}C$ for 25 hours. Nickel and oxygen were detected from the corrosion products on the surface of Inconel plates and chromium was found to be dissolved out into lithium molten salts leaving cracks on the surface. The corrosion products were identified as metal oxides such as Fe$_2$O$_3$, Cr$_2$O$_3$, NiO, NiFe$_2$O$_4$and MnO by using XPS and XRD.