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One-Pot Synthesis of Clay-dispersed Poly(styrene-co-acrylonitrile) Copolymer Nanocomposite using Poly($varepsilon$-caprolactone) as a Compatibilizer
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  • One-Pot Synthesis of Clay-dispersed Poly(styrene-co-acrylonitrile) Copolymer Nanocomposite using Poly($varepsilon$-caprolactone) as a Compatibilizer
  • One-Pot Synthesis of Clay-dispersed Poly(styrene-co-acrylonitrile) Copolymer Nanocomposite using Poly($varepsilon$-caprolactone) as a Compatibilizer
저자명
Ko. Moon-Bae
간행물명
Korea Polymer Journal
권/호정보
2000년|8권 4호|pp.186-191 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Clay-dispersed nanocomposites have been prepared by simple melt-mixing of three components, i.e. poly (styrene co-acrylonitrile) copolymer (SAN), poly ($xi$-caprolactone ) (PCL), and an organophilic clay(Cloisite(R) 30A). In the present study, poly($xi$-caprolactone) was added in the mixtures in order to facilitate the intercalation of SAN into the gallery of silicate layers, and the molecular weight effects of PCL on the dispersion of silicate layers were compared by changing the amount of added PCL. The degree of dispersion of 10-$AA$-thick silicate layers of clay in the nanocomposites was investigated by using an X-ray diffractometer and a transmission electron microscope. It was found that PCL added in the mixture facilitate the intercalation of SAN copolymers into the galleries of silicate layers modified with an organic intercalant, resulting in the better dispersion of clay. It was, also, observed that the processing temperature influences the degree of clay dispersion.