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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals
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  • A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals
  • A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals
저자명
박진남,김재현,이호인,Park. Jin Nam,Kim. Jae Hyeon,Lee. Ho In
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2000년|21권 12호|pp.1233-1238 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

$Mo/{gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${ hickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.