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UV-Degradation Chemistry of Oriental Lacquer Coating Containing Hindered Amine Light Stabilizer
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  • UV-Degradation Chemistry of Oriental Lacquer Coating Containing Hindered Amine Light Stabilizer
  • UV-Degradation Chemistry of Oriental Lacquer Coating Containing Hindered Amine Light Stabilizer
저자명
홍진후,박미영,김현경,최정오,Hong. Jin Hu,Park. Mi Yeong,Kim. Hyeon Gyeong,Choe. Jeong O
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2000년|21권 1호|pp.61-64 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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FT-IR/ATR analysis shows that the oriental lacquer coating network degrades mostly in the unsaturated side chain. The rate of increase in carbonyl intensity (a measure of photodegradation) during the accelerated weathering test was substantially different for the unstabilized and stabilized samples; adding 2 wt% HALS into the oriental lacquer formulation enhanced photostabilization up to three times. Weight loss measurements, another indication of photodegradation, and SEM analysis support this conclusion. Despite the presence of the photo-stabilizer, the other properties of the lacquer were not significantly affected. In particular, the curing behavior of purified lacquer (PL) and HALS-stabilized samples is similar, although the in-situ DETA analysis showed that addition of HALS can slightly retard the cure reaction rate in oriental lacquer coating. It is hypothesized that this cure retardation may be related to the salt formation between HALS and acid of oriental lacquer.