This paper describes a system that can used to recognize an unknown material regardless of the change of ambient tem-perature using temperature response curve fitting and fuzzy neural network(FNN). There are some problems to realize the recogni-tion system using temperature response. It requires too many memories to store the vast temperature response data and it has to be filtered to remove noise which occurs in experiment. And the temperature response is influenced by the change of ambient tempera-ture. So, this paper proposes a practical method using curve fitting the remove above problems of memories and nose. And FNN is propose to overcome the problem caused by the change of ambient temperature. Using the FNN which is learned by temperature responses on fixed ambient temperature and known thermal conductivity, the thermal conductivity of the material can be inferred on various ambient temperature. So the material can be recognized by the thermal conductivity.