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Poly(trimethylene terephthalate) 섬유의 고속방사에 따른 미세구조 형성과 물성
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  • Poly(trimethylene terephthalate) 섬유의 고속방사에 따른 미세구조 형성과 물성
  • Fine Structure Formation and Property Changes of Poly(trimethylene terephthalate) Fibers Obtained by High-Speed Melt Spinning
저자명
조현혹,주시환
간행물명
韓國纖維工學會誌
권/호정보
2001년|38권 9호|pp.429-438 (10 pages)
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한국섬유공학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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PTT polymer was spun by high-speed melt spinning method, and the effects of take-up velocity and mass flow rate on the fiber structure and properties were investigated. The changes in the structure and property with take-up velocities were studied by measuring WAXD, DSC, density, birefringence, dynamic viscoelasticity and tensile test, etc. The orientation in crystalline phase obtained by WASD increased with the increase of take-up velocity. The orientation-induced crystallization of PTT fibers in high-speed melt spinning appeared at the take-up velocity of about 3~4km/min. This tendency was confirmed by the results of DSC thermograms, density, and birefringence. The birefringence increased abruptly up to take-up velocity of 4km/min, but it became almost constant when the take-up velocity exceeded 4km/min. The tendency was confirmed by the result of dynamic viscoelasticity. The maximum point of $alpha$$_{c}$-dispersion shifted to a higher temperature, but shifted to a lower temperature when the take-up velocity exceeded 4 km/min. The fine structure and the mechanical properties were not affected significantly by mass flow rate.e.