The fuels of water-in-oil emulsion have a potential of reducing PM(Particulate Matter) and NOx emissions, and increasing combustion efficiency in the furnaces and the burners. For making the most of the beneficial of the secondary atomization due to the microexplosion, the water droplets distributed in the oil must have the optimal sizes. The purpose of this paper is to investigate the water droplet size distribution characteristics of the different types of the static mixers. For analysis the size distribution characteristics efficiently, image analysis system wes constructed and an appropriate image processing algorithm was developed. Two kinds of static mixers: Kenics type and RF type, were tested. As a results, RF type static mixer shows a better characteristics in the mean drop size, particularly in the condition of high water content.