- 수화한 무정형 알루미나로부터 제조된 $gamma$-Alumina의 특성
- ㆍ 저자명
- 김윤섭,고형신,서정권,이정민,하백현,Kim. Yun-Seop,Go. Hyeong-Sin,Seo. Jeong-Gwon,Lee. Jeong-Min,Ha. Baek-Hyeon
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2001년|11권 11호|pp.978-985 (8 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The amorphous alumina was obtained by flash calcination of Bayer gibbsite[$Al(OH)_3$aluminum trihydroxide]. Rehydration and pore characteristics of $r-A1_2O_3$ prepared from rehydrated amorphous alumina were investigated. Crystal phases of pseudo-boehmite and bayerite were changed when amorphous alumina was hydrated at various conditions such as time, the ratio of water/alumina and pH. Specific surface areas and pore volumes of $r- A1_{2O}_3$ were influenced by the reaction time, water/alumina and PH of rehydration. The total pore volume of $r-A1_{2O}_3$increases with increasing the reaction time and ratio of water/alumina. Especially, the pure pseudo-boehmite of single phase could be prepared, when amorphous alumina was hydrated in the range of pH 6.5-8.0 in water/alumina= 10 at $90^{circ}C$ for 7hr. The $r-Al_{2O}_3$, obtained by calcination of the prepared pseudo-boehmite at $500^{circ}C$ for 2hrs, is characterized by the specific surface area of $265m^2$/g, total pore volume of $0.75cm^3$/g.