In this study, it is observed that the distribution of combustion chamber volume affects the volumetric efficiency. The distribution ratio was adjusted by controlling combustion chamber volume of head and piston bowl one. Four cases were investigated, which are the combination of different distribution ratios and different compression ratios (9.8-10.0). A commercial SOHC 3-valve engine was modified by cutting the bottom face of the head and/or replacing the piston by the one that has different volume. The result shows that the less the head side volume, the more volumetric efficiency is achieved under the same compression ratio. It is also observed that increasing volumetric efficiency results in early knock occurrence due to increased "real" compression ratio. To consider reliability in estimating the volumetric efficiency, we examined the sensitivity of the AFR equation to possible errors in emission measurements. It is shown that the volumetric efficiency, which is calculated by measuring AFR and fuel consumption, can be controlled in 1% error. 1% error.