In the present study, the internal combustion engine tends to high performance, fuel economy, small-sized. Therefore, it is necessary to solve the problems on thermal load, abnormal combustion, etc in the engine. Thin film instantaneous temperature probe was made, and the measuring system was established. The instantaneous surface temperatures in the constant volume combustion chamber were measured with this system and the heat flux was obtained by Fourier analysis. Maximum instantaneous temperatures were obtained after 55∼60ms from ignition and they increased as equivalence ratio and varied differently as the position of probe. Total heat loss during combustion time was affected by the equivalence ratio and differed widely as the position of probe.