The effect of air entrainment in twin-fluid spray structure is investigated experimentally by varing the amount of itemizing air. The air entrainment is expected to affect on droplet size and velocity, droplet number density, turbulent kinetic energy and vorticity. PDA(Phase Doppler Anemometer) and PIV(Particle Image Velocimetry) system are used to measure those important factors in analyzing spray structure. The results show that spray structure consists of three distinctive regions ; the atomizing region near nozzle, characterizing strong convective effect, the central core region where droplets are accelerated, and the spray sheath region where droplets are decelerated due to air entrainment. The local air entrainment rate is largest near nozzle, characterizing strong turbulent kinetic energy and vorticity but deceases along axial distance.