Syntactic ambiguity can be understood by context usually, especially in reading and writing. Because phonological structure including stress, intonation and phonological phenomena can be pronounced differently according to different syntactic structures, syntactic ambiguity can be solved by phonological structure in listening and speaking. The objectives of this study was to survey how Korean English teachers apply phonological structures in order to solve syntactic ambiguity. The results of this study is as follows: First, Korean English leachers applied Compound Stress Rules well, when the second word was not branched. But they did not apply Compound Stress Rules well, when the second word was branched. Second, several Korean English teachers did not apply Nuclear Stress Rules well. They usually put the strongest stress on the first word. Third Korean English teachers did not differentiate appropriate applying situation of palatalization. They applied palatalization at both the single and the separated Phonological Phrase. Fourth, Korean English teachers did not apply stress shifting when stress crash happened. Because they did not apply stress shifting, they put the strongest stress on inappropriate syllable.