- 환원제로 차아인산나트륨을 사용한 무전해 동도금속도에 미치는 도금액 조성과 도금조건의 영향
- ㆍ 저자명
- 오이식,박정덕,배영한,Oh. I.S,Park. J.D.,Bai. Y.H.
- ㆍ 간행물명
- 한국동력기계공학회지
- ㆍ 권/호정보
- 2001년|5권 2호|pp.71-78 (8 pages)
- ㆍ 발행정보
- 한국동력기계공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Using sodium hypophosphite as reducing agent, bath composition and plating condition of electroless copper plating on plating rate have been studied. The followings were determined as optimum, bath composition; $CuSO_4;0.025M,;NiSO_4;0.002M,;NaH_2PO_2;0.4M$, sodium citrate 0.06M, $H_3BO_3$ 0.6M, thiourea or 2-MBT $0.2mg/{ell}$, and operation conditions; pH $9{sim}10$ at bath temperature rage of $60{sim}70^{circ}C$. A small amount of nickel ion($Ni^{2+}/Cu^{2+}$=0.002/0.025) to the hypophosphite reduced solution promotes autocatalysis and continuous plating. An additive such as thiourea or 2-MBT of a small amount($0.2mg/{ell}$) can be used to stabilize the solution without changing plating rate much. The attivation energy between $20^{circ}C;and;70^{circ}C$ were calculated to be 11.3kcal/mol for deposition weight. Plating reaction had been ceased by the adjustment of pH above 13, temperature higher than $90^{circ}C;and;under;20^{circ}C$. Deposited surface became worse in the case of increment of bath temperature above $80^{circ}C$.