Commercial titanium rod was anodized in three types of electrolytes such as 0.06 mol/L $eta-glycerophosphate+0.3mol/L$ calcium acetate, 0.06mol/L $eta-glycerophosphate+0.3mol/L$ sodium acetate and 0.06 mol/L $eta-glycerophosphate+5mol/L$ calcium phosphate. The titanium oxide layer $(TiO_2)$ was characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and electron spectroscopy chemical analysis (ESCA). Numerous micropores were observed on the titanium oxide layer by SEM. The diameter of micropores increased with the increase of electrolytic voltage. The titanium oxide layer was composed of anatase structure. The phosphorous element was detected at 130 eV binding energy, but calcium was not found in the oxide layer because of lower contents. After anodizing the oxide layer was etched in the 30g/L NaOH solution at $80^{circ}C$ for 1hr. The surroundings of micropores were much more smoothed and rounded than before alkaline etching.