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Relationships between the Raman Excitation Photon Energies and Its Wavenumbers in Doped trans-Polyacetylene
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  • Relationships between the Raman Excitation Photon Energies and Its Wavenumbers in Doped trans-Polyacetylene
  • Relationships between the Raman Excitation Photon Energies and Its Wavenumbers in Doped trans-Polyacetylene
저자명
Kim. Jin-Yeol,Kim. Eung-Ryul,Ihm. Dae-Woo,Tasumi. Mitsuo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2002년|23권 10호|pp.1404-1408 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The resonance Raman spectra of trans-polyacetylene films doped heavily with electron donor (Na) and acceptor (HClO4) have been measured with excitation wavelengths between 488- and 1320-nm, and the relationships between the Raman excitation photon energies (2.54-0.94 eV) and its wavenumbers were discussed. We found the linear dependence of the Raman shifts with the exchanges of excitation photon energies. In particular, the Raman wavenumbers in the C=C stretching $(V_1$ band) showed a dramatic decrease with the increase in Raman excitation photon energies. In the case of acceptor doping, its change is larger than that of donor doping. The observed wavenumber (1255-1267 $cm^{-1}$) of the $V_2$ band (CC stretch) of Na-doped form is lower than that of the corresponding band (1290-1292 $cm^{-1}$) of its pristine trans-polyacetylene, whereas the contrary is the case for the HClO4 doped form (1295-1300 $cm^{-1}$). The origin of doping-induced Raman bands is discussed in terms of negative and positive polarons.