An experimental study has been carried on high-preheated temperature air combustion. The flames with high-preheated temperature air combustion turned out to be both temporally and spatially much more stable and homogeneous than these with room-temperature combustion air. The global flame feature showed a range of flame colors (yellow, blue, blurish-green) according to the flame conditions. A low level of NOx along with low level of CO has been obtained under high-preheated air combustion conditions. The thermal and chemical behavior of high-preheated air combustion flames depends on the preheated temperature and the oxygen concentration of air.