The probability density functions (PDF) of temperature were measured by coherent anti-Stokes Raman Spectroscopy (CARS) in flames of gas turbine combustor sector rig of an aero-engine. The combustor was operated at simulated ground idle conditions with standard kerosene fuel. Temperature PDFs had been measured near fuel nozzle with change of rotation of a swirler and existence of a prefilmer. The characteristic features of temperature PDFs showed the variation of combustion configurations at four experimental conditions. Without a prefilmer, large recirculation of high temperature gas was expected in the co-flow condition and un vaporized fuel fragments were detected in the counter-flow condition. With a prefilmer, the enhanced mixing increased combustion intensity near fuel nozzle in the counter-flow condition and the flame was attached far from the fuel nozzle in the co-flow condition.