It was virtually declared that measurement science must abandon the error analysis of measurement when ISO had published "Guide to Expression of uncertainty in Measurement" International inclination of measurement field in order to guarantee the traceability and confidence of measurement results discards the error concept and instead analyzes the measurement uncertainty. In this paper we establish a mathematical model of measurement and analyze all uncertainty factors as possible as for yielding the measurement uncertainty in the course of the calibration of RF multimeter using Transfer Standard, Thermal Voltage Converter We produce the expanded uncertainty by analyzing cable effects, correlation of thermocoupler and DC meter, DC source, RF source, attenuator, reflection coefficients and DUT.s and DUT.