The coupled model (SMART) of dynamic meteorology model and particle dispersion model was developed. The numerical experiment on the relationship between change of land use and diffusion behavior in complex terrain was carried out using this model. It tried to investigate the change of particle diffusion behavior and local weather under the condition in which land-land breeze and sea breeze and mountain breeze intermingled. The numerical experiment results are as follows; 1) The more complicated local circulation field of the interaction of sea breeze, mountain breeze and Land -land breeze is formed. Then, the region circulation in which the urbanization is specific by location of the region is strengthened and is weakened. 2) Though in the region with dominant sea breeze, Land-land breeze does not appear directly, the progress of the sea wind to the inland is affected. 3) In the prediction of the air diffusion, emission high quality and accurate information of the emission site are important. That is to say, the dispersion predicting result which emission high quality and small error of the site perfectly vary for Land - land breeze in the effect may be brought about.