Improvements of fuel properties have become essential for exhaust emission reduction as well as for optimization of directly-related design factors and exhaust gas aftertreatment. In this study, the potential possibility of oxygenated fuel such as ethylene glycol mono-n-butyl ether(EGBE) was investigated for the sake of smoke reduction from diesel engine. Because EGBE include oxygen content approximately 27%, it is a kind of effective oxygenated fuel that the smoke emission of EGBE is reduced remarkably in comparison with commercial diesel fuel, that is, it can supply oxygen component sufficient at high load and speed in diesel engine. And, it was tried to analyze the quantities of the low and high boiling point hydrocarbon among the exhaust emissions in diesel engine. It have been investigated by the quantitative analysis of the hydrocarbon $C_1$~ $C_{6}$ using the gas chromatography. This study was carried out by comparing the chromatogram with diesel fuel and diesel fuel blended EGBE 20vo1-%. The results of this study show that the hydrocarbon $C_1$~C$_{6}$ among the exhaust emission of the mixed fuels are exhausted lower than those of the diesel fuel at the all load and speed. In particular, high boiling point hydrocarbons such as $C_{5}$ and $C_{6}$ were reduced remarkably at high speed and load.d.