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서지반출
Structure Development and Dynamic Properties in High-speed Spinning of High Molecular Weight PEN/PET Copolyester Fibers
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  • Structure Development and Dynamic Properties in High-speed Spinning of High Molecular Weight PEN/PET Copolyester Fibers
  • Structure Development and Dynamic Properties in High-speed Spinning of High Molecular Weight PEN/PET Copolyester Fibers
저자명
Im. Seung-Soon,Kim. Sung-Joong
간행물명
Fibers and polymers
권/호정보
2002년|3권 1호|pp.18-23 (6 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The structure development and dynamic properties of fibers produced by high-speed spinning of P(EN-ET) random copolymers were investigated. The as-spun fibers were found to remain amorphous up to the spinning speed of 1500 m/min, and subsequent increases in speed resulted in the crystalline domains containing primarily $alpha$ crystalline modification of PEN. The f modification was not found up to spinning speeds of 4500 m/min. On the other hand, annealing of constrained fibers spun at the 2100 m/min at 180,200, and 240^{circ}C$ exhibited $eta$-form crystalline structure, while the annealed fibers spun in 600-1500 m/min range exhibited dominantly $alpha$-form. However $eta$-form crystals disappeared above the spinning speed of 3000 m/min. With increasing spinning speeds from 600 to 4500 m/min, the storage modulus of as-spun fibers increased continuously and reached a value of about 10.4 spa at room temperature. The tan $delta$curves showed the $alpha$-relaxation peak at about 155-165^{circ}C$, which is considered to correspond to the glass transition. The $alpha$-relaxation peaks became smaller and broader, and shift to higher temperatures as the spinning speed increases, meaning that molecular mobility in the amorphous region is restricted by increased crystalline domain.