A field study was conducted to estimate the emission rate of biogenic volatile organic compounds (BVOCs) from pine trees. In addition, the influences of meteological variables on their distribution characteristics have been investigated. A vegetation enclosure chamber was designed and constructed of Tedlar bag and acril. Sorbent tubes made up of Tenax TA and Carbotrap were used to collect biogenic VOCs emitted from each individual tree. Analysis of BVOCs was performed using a GC-FID system. The fundamental analytical parameters including linearity, retention time, recovery efficiency, and breakthrough volume were examined and verified for the determination of monoterpene emission rates. Total average concentration of each component is found to be $alpha$-pinene (16.5), $eta$-pinene (4.61) from pine trees, and $alpha$-pinene (42.4), $eta$-pinene (18.7 ng(gdw)$^{-1}$ hr$^{-1}$ ) from Korean pine trees. On the basis of our study, $alpha$-pinene was found to be the major monoterpene emitted from both pine and Korean pine trees which were accompanied by $eta$-pinene, camphene, and limonene. In ambient air, variable monoterpene compositions of emissions from pine trees were similar to Korean pine trees. Emission rates of monoterpene from each tree were found to depend on such parameters as temperature and solar radiation.