Coating ceramic balls activate water molecular in water as radiate far-infrared radiation of high efficiency, and then prevent formation of scale and corrosion of pipe. Therefore, but only keep away drop of heat exchange efficiency of boiler, not also remove formed scale. As a result, pipe of boiler has clean and has form thin protection film in inner of pipe. Also, the water treated by rust preventing system using the ceramic balls, that is harmless, tasteless, odorless, and non-toxicity in the human body, and it can use drinking water. This rust preventing system can save energy and protect environment.