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Preparation, Characterization, and Gas Permeation Properties of Carbon Molecular Sieve Membranes Derived from Dense P84-Polyimide Film
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  • Preparation, Characterization, and Gas Permeation Properties of Carbon Molecular Sieve Membranes Derived from Dense P84-Polyimide Film
  • Preparation, Characterization, and Gas Permeation Properties of Carbon Molecular Sieve Membranes Derived from Dense P84-Polyimide Film
저자명
Park. Ho-Bum,Nam. Sang-Yong,Jang. Jeong-Gyu,Lee. Young-Moo
간행물명
Korean membrane journal
권/호정보
2002년|4권 1호|pp.25-35 (11 pages)
발행정보
한국막학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The gas permeation properties have been studied on carbon molecular sieve (CMS) membranes prepared by pyrolysis of P84 polyimide under various conditions. P84 polyimide shows high permselectivities (O$_2$/N$_2$= 9.17 and CO$_2$/N$_2$= 35) for various gas pairs and has a good processibility because it is easily soluble in high polar solvents such as N-methylpyrrolidinone (NMP), dimethylformamide (DMF), and N,N-dimethylacetamide (DMAc). After pyrolysis under Ar flow, the change in the heating rate was found to affect the gas permeation properties to some extent. The permeabilities of the selected gases were shown to be in the order He > CO$_2$> O$_2$> N$_2$for all the CMS membranes, whose order was in accordance with the order of kinetic gas diameters. It also revealed that the pyrolysis temperature considerably influenced the gas permeation properties of the CMS membranes derived from P84 polyimide. The CMS membranes pyrolized at 700$^{C}$ temperature exhibited the highest permeability with relatively targe loss in permselectivity. This means that the pyrolysis temperature should be varied in accordance with target gases to be separated.