This study classifies Korean syllables into various types and investigates the distribution of syllables by each type. Korean syllables are classified into four or eight types. In this study, they are classified into thirty-two types based on character combination in order to evaluate the intelligibility of Korean synthetic syllables. Among those Korean syllables derived from the possible combinations of Korean characters, only currently used syllables were selected. Based on this classification and distribution, representative and diagnosable testing materials can be made. These testing materials can be applicable to intelligibility tests of Korean synthetic syllables.