This study is to investigate the wear behaviors of thermally sprayed ceramic coating by a pin-on-disk wear testing machine. The test specimens were plasma sprayed TiO2 coating material on carbon steel substrate(S45C) with Ni-4.5%Al alloy bond coating. Wear characteristics, friction coefficient and wear rates, were conducted at the three kinds of loads and velosities. Wear environments were dry and lubrication friction. The friction coefficients of TiO2 coating specimen in dry friction were almost same according to increase the friction velocity. The wear rate increased when the friction force is high. In lubrication friction, the wear hardly occured and friction coefficient was about 0.1. The adhesiveness of TiO2 in lubrication friction is larger than that in dry one.