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Preparation and Characterization of Poly(butyl acrylate)/Poly(methyl methacrylate) Composite Latex by Seeded Emulsion Polymerization
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  • Preparation and Characterization of Poly(butyl acrylate)/Poly(methyl methacrylate) Composite Latex by Seeded Emulsion Polymerization
  • Preparation and Characterization of Poly(butyl acrylate)/Poly(methyl methacrylate) Composite Latex by Seeded Emulsion Polymerization
저자명
Ju. In-Ho,Hong. Jin-Ho,Park. Min-Seok,Wu. Jong-Pyo
간행물명
한국유화학회지
권/호정보
2002년|19권 2호|pp.131-136 (6 pages)
발행정보
한국유화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

As model waterborne acrylic coatings, mono-dispersed poly(butyl acrylate-methyl methacrylate) copolymer latexes of random copolymer and core/shell type graft copolymer were prepared by seeded multi-staged emulsion polymerization with particle size of $180{sim}200$ nm using semi-batch type process. Sodium lauryl sulfate and potassium persulfate were used as an emulsifier and an initiator, respectively. The effect of particle texture including core/shell phase ratio, glass transition temperature and crosslinking density, and film forming temperature on the film formation and final properties of film was investigated using SEM, AFM, and UV in this study. The film formation behavior of model latex was traced simultaneously by the weight loss measurement and by the change of tensile properties and UV transmittance during the entire course of film formation. It was found that the increased glass transition temperature and higher crosslinking degree of latex resulted in the delay of the onset of coalescence of particles by interdiffusion during film forming process. This can be explained qualitatively in terms of diffusion rate of polymer chains. However, the change of weight loss during film formation was insensitive to discern each film forming stages-I, II and III.