An experimental study has been conducted to investigate the heat/mass transfer characteristics within a square film cooling hole with asymmetric inlet now condition. The asymmetric inlet now condition is achieved by making distances between side walls of the secondary now duct and the film cooling hole different; one side wall is $2D_h$ apart from the center of the film cooling hole, while the other side wall is $1.5D_h$ apart from the center of the film cooling hole. The heat/mass transfer experiments for this study have been performed using a naphthalene sublimation method and the now field has been analyzed by numerical calculation using a commercial code. Swirl now is generated at the inlet region and the heat/mass transfer pattem with the asymmetric inlet now condition is changed significantly from that with the symmetric condition. In the exit region, the effect of mainstream on the inside hole now is reduced with the asymmetric condition. The average heat/mass transfer coefficient is higher than that with the symmetric condition due to the swirl now generated by the asymmetric inlet condition.