To improve the fuel consumption and exhaust emission for gasoline engines, GDI(Gasoline Direct Injection) system was spotlighted to solve above requirements. Thus, many researchers have been studied to investigate the spray characteristics and the mixture formation of GDI injector. In this study, we tried to study the spray characteristics of a gasoline direct injector by using entropy analysis and PlV methods. The entropy analysis is based on the concept of statistical entropy, and it identifies the degree of homogeneity in the fuel concentration. The PlV method was adopted to determine the fluid dynamics information at the spray. From the applied results on a direct injection gasoline spray, we could find that the direct diffusion phenomena was a dominant factor in the formation of a homogeneous mixture at downstream of GDI spray especially under vaporizing ambient conditions, and mixing phenomena was also progressed by momentum exchange with induced air. In addition, the correlation between entropy and vorticity strength enabled to find their relation.