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EVA/Clay Nanocomposite by Solution Blending: Effect of Aluminosilicate Layers on Mechanical and Thermal Properties
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  • EVA/Clay Nanocomposite by Solution Blending: Effect of Aluminosilicate Layers on Mechanical and Thermal Properties
  • EVA/Clay Nanocomposite by Solution Blending: Effect of Aluminosilicate Layers on Mechanical and Thermal Properties
저자명
Pramanik. M.,Srivastava. S.K.,Samantaray. B.K.,Bhowmick. A.K.
간행물명
Macromolecular research
권/호정보
2003년|11권 4호|pp.260-266 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Ethylene vinyl acetate (EVA)/clay nanocomposites were synthesized by blending a solution of ethylene vinyl acetate copolymer containing 12% vinyl acetate abbreviated as EVA-12 in toluene and dispersion of dodecyl ammonium ion intercalated montmorillonite (l2Me-MMT) in N,N-dimethyl acetamide (DMAc). X-ray patterns of sodium montmorillonite ($Na^+$-MMT) and 12Me-MMT exhibited $d_{001}$ peak at $2{ heta}=7.4^{circ}$ and $2{ heta}=5.6^{circ}$ respectively; that is, the interlayer spacing of MMT increased by about 0.39 nm due to intercalation of dodecyl ammonium ions. The XRD trace of EVA showed no peak in the angular range of $3-10^{circ}(2{ heta})$. In the XRD patterns of EVA/clay hybrids with clay content up to 6 wt% the basal reflection peak of 12Me-MMT was absent. leading to the formation of delaminated configuration of the composites. When the 12Me-MMT content was 8 wt% in the EVA-12 matrix, the hybrid revealed a peak at about $2{ heta}=5.6^{circ}$, owing to the aggregation of aluminosilicate layers. Transmission electron microscopic photograph exhibited that an average size of 12-15 nm clay layers were randomly and homogeneously dispersed in the polymer matrix, which led to the formation of nanocomposite with delaminated configuration. The formation of delaminated nanocomposites was manifested through the enhancement of mechanical properties and thermal stability, e.g. tensile strength of an hybrid containing only 2 wt% 12Me-MMT was enhanced by about 36% as compared with neat EVA-12.