The purpose of this work is to investigate the effect of premixed fuel on the reduction of exhaust emissions in premixed charge compression ignition engine. The premixed fuel is injected into the intake manifold to form homogeneous pre-mixture in the combustion chamber. The pre-mixture is ignited by a small amount of diesel fuel directly injected into the cylinder. In the case of gasoline as a premixed fuel of the engine, $NO_x$ and smoke concentration of exhaust emissions were reduced compared with the conventional diesel engine. But in the event of diesel fuel for premixed fuel, the rate of smoke reduction was small compared with the case of gasoline as a premixed fuel. HC and CO emissions were increased at high premixed ratio in the case of two premixed fuels. The combustion characteristics of the engine such as the combustion pressure, the rate of heat release, and other characteristics are compared.