Recently, LPLi(Liquied-Phase LPG injection) system is studied for the new stringent emission regulations. But , there are some problems to be solved such as injector tip icing and fuel leakage for LPLi system development. In this paper, the icing problem near injector tip which leads to difficulty of accurate A/F control was studied and reported. Icing of injector tip and port wall was observed at all the cases in this study regardless of injection duration and angle, air humidity change. The spray angle of LPLi was observed approximately two times wider than that of Gasoline injection. This makes the LPLi spray collide with intake port around injector tip. Temperature of the wetted area was decreased and icing of water vapor contained in intake air because of evaporation of the fuel film. The ice of the injector tip and port wall is also affected by the materials related to heat transfer.