- 도시 대기 중 PM10에 함유된 다환방향족탄화수소의 농도분포특성과 주요 영향인자
- ㆍ 저자명
- 최진수,백성옥
- ㆍ 간행물명
- 한국대기환경학회지
- ㆍ 권/호정보
- 2003년|19권 1호|pp.33-44 (12 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The atmospheric concentrations of particulate polycyclic aromatic hydrocarbons (PAHs) associated with PM$_{10}$ were determined in Taegu metropolitan area. Sampling was undertaken every five days throughout one year period from 1993 to 1994 at four sites, representing a residential, a commercial, an industrial, and a sub-urban area, respectively. Benzo (e) pyrene, benzo (k) fluoranthene, and chrysene were found to be the most abundant com-pounds during the study period. The concentrations of benzo (a) pyrene, one of carcinogenic PAHs, ranged 2.0~4.8 ng/㎥ in winter and 0.5~1.5 ng/㎥ in summer season, indicating a marked seasonal variation. It was found that there were very similar patterns in the relative profiles of PM$_{10}$-bound PAH concentrations among the four sampling sites, while the absolute levels of each PAH were significantly different from each site. In addition, the patterns of summer to winter concentration ratios for each PAH were almost identical between the different sites. Despite difficulties due to the lack of good markers for specific sources in the target compounds, we were able to evaluate and describe the effects of vehicle emissions and space heatings, using relative profiles of PAHs, winter to summer (W/S) ratios, PAH-to-PAH ratios, and the result of principal component analysis. As a con-sequence, it was concluded that the vehicle emissions in urban and sub -urban areas are likely to be a major contributor for PAH loadings in the ambient atmosphere during the non-heating season, while the contributions of residential heating and local industrial oil burning emissions were highly significant in heating season.son.