Power system is analyzed by three methods of load flow, fault calculation, and voltage stability. Among there, load flow is calculated to flow of power in power in system at steady state. But, load flow is difficult to analyze to flow of power in substation, because power flow frequently alter by various equipments such as circuit bleaker, disconnect switch and shunt reactor. Particular, in 765[㎸] system, because of form of 1.5GB for stable operation, structure of substation has been very complex. In this paper, we describe technique for application of load flow algorithm in simulator for 765[㎸] substation. For this technique, we built each database for various equipments and considered form of 1.5GB Data as form of bus and line, for application of load flow, are acquired from built database, and then calculate load flow in substation. And. results of load flow are outputted in screen of operator console program.