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A Molecular Dynamics Simulation on the Self-assembly of ABC Triblock Copolymers.3. Effects of Block Composition in Asymmetric Triblock Copolymers
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  • A Molecular Dynamics Simulation on the Self-assembly of ABC Triblock Copolymers.3. Effects of Block Composition in Asymmetric Triblock Copolymers
  • A Molecular Dynamics Simulation on the Self-assembly of ABC Triblock Copolymers.3. Effects of Block Composition in Asymmetric Triblock Copolymers
저자명
Ko. Min-Jae,Kim. Seung-Hyun,Jo. Won-Ho
간행물명
Fibers and polymers
권/호정보
2003년|4권 1호|pp.15-19 (5 pages)
발행정보
한국섬유공학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The self-assembly of asymmetric ABC triblock copolymers in the ordered structure is investigated using an isothermal-isobaric molecular dynamics simulation. Unlike symmetric A BC triblock copolymers, more fascinating mophologies are observed in asymmetric ones because of a larger difference of incompatibility between the components. Various modes of self-assembly in assymmetric ABC triblock copolymers are also observed depending on the block composition. When the composition of block A Is changed from 0.125: to 0.25 at the same $f_B$ : 0.25, the morphological transition from the “cylinder in cylinder” to “cylinders at cylinder” structure is observed in the simulation. In the case of ABC triblocks with $f_B$=0.5, a lamellar-type structure is changed to a cylinder-type structure with increasing the length of block A. When the midblock length increases further to $f_B$=0.625, the “spheres on cylinder” structure is observed in both the $A_{10}$$B_{50}$$C_{20}$ and $A_{20}$$B_{50}$$C_{10}$ triblocks. From these results, the phase diagram of ABC triblock copolymers can be constructed.