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Roles of Phosphoric Acid in Slurry for Cu and TaN CMP
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  • Roles of Phosphoric Acid in Slurry for Cu and TaN CMP
  • Roles of Phosphoric Acid in Slurry for Cu and TaN CMP
저자명
Kim. Sang-Yong,Lim. Jong-Heun,Yu. Chong-Hee,Kim. Nam-Hoon,Chang. Eui-Goo
간행물명
Transactions on electrical and electronic materials
권/호정보
2003년|4권 2호|pp.1-4 (4 pages)
발행정보
한국전기전자재료학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$^$nd/ step copper CMP slurry and hydrogen peroxide stability.