This paper presents a study on the permittivities of the I-glass fabric/epoxy composite laminates containing carbon black dispersions at microwave frequency. Measurements were performed at the frequency band of 5 GHz∼18 GHz. The results showed that the complex permittivities of the composites depend strongly on the natures and concentrations of the carbon black dispersion. A new scheme is proposed to obtain a mixing law for the estimation of the complex permittivities of the composite laminates as a function of concentration of carbon black. Simultaneously, the complex permittivity of carbon black itself was also calculated by the scheme. The experimental values of the complex permittivities of the composites were compared to those calculated.